Reactivity of antimony mixed halides for the fluorination of tetrachlorethene (PCE) in liquid phase

被引：4

作者：

Brunet, S ^{[1
]}

Batiot, C ^{[1
]}

Moriceau, P ^{[1
]}

Thybaud, N ^{[1
]}

机构：

[1] Univ Poitiers, UMR 6503 CNRS, F-86022 Poitiers, France

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 142卷 / 02期

关键词：

fluorination; tetrachlorethene; Lewis acid; antimony;

D O I：

10.1016/S1381-1169(98)00293-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The active species for the liquid phase fluorination of tetrachloroethene (PCE) was produced by in situ reaction between HF and SbCl5. By comparison with various commercial antimony mixed halides (SbCl4F, SbC3F2, SbCl3F2 and SbClF4), the active species, produced in situ in our conditions, could be composed by SbCl4F or/and SbCl3F2 or a mixture of both. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：183 / 186

页数：4

共 10 条

[1] CATALYTIC LIQUID-PHASE FLUORINATION OF TETRACHLORETHENE (PCE) WITH TITANIUM ANTIMONY MIXED HALIDES [J].