Effect of precursor type on the microstructure of PbTiO3 thin films

被引：22

作者：

Malic, B ^{[1
]}

Kosec, M ^{[1
]}

Smolej, K ^{[1
]}

Stavber, S ^{[1
]}

机构：

[1] Jozef Stefan Inst, Ljubljana 1000, Slovenia

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 1999年 / 19卷 / 6-7期

关键词：

PbTiO3; precursors-organic; sol-gel processes; films; microstructure-final;

D O I：

10.1016/S0955-2219(98)00431-2

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Lead-titanium solution precursors were prepared by (i) preceding syntheses of the lead precursor by reaction of lead acetate with 2-methoxyethanol and titanium methoxyethoxide and their subsequent reaction, (ii) reaction between anhydrous lead acetate and titanium methoxyethoxide, (iii) reaction between lean oxide and titanium methoxyethoxide in 2-methoxyethanol as a common solvent. The lead acetate-derived precursor exhibits a complex thermal decomposition with the highest weight loss, while smooth pyrolysis with the lowest weight loss characterises the lead-oxide-derived precursor. Variations in precursor structure affect the pyrolysis behaviour, thickness and microstructure of as-deposited lead titanate thin films. (C) 1999 Elsevier Science Limited. All rights reserved.

引用

页码：1345 / 1348

页数：4

共 10 条

[1]

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