Influence of site percolation and local distortion on lithium ion conductivity in perovskite-type oxides La0.55Li0.35-xKxTiO3 and La0.55Li0.35TiO3-KMO(3) (M=Nb and Ta)

被引：47

作者：

Katsumata, T

Matsui, Y

Inaguma, Y

Itoh, M

机构：

[1] Res. Lab. of Engineering Materials, Tokyo Institute of Technology, Yokohama 226, 4259 Ngatsuda, Midori-ku

来源：

SOLID STATE IONICS | 1996年 / 86-8卷

关键词：

lithium ion conductivity; perovskite-type oxide; site percolation; local distortion; bottleneck size;

D O I：

10.1016/0167-2738(96)00116-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In order to attain a higher lithium ion conductivity in perovskite-type oxide the effect of elemental substitution was investigated for solid solution systems (1-x)La0.55Li0.35TiO3-xKNbO(3), (1-x)La0.55Li0.35TiO3-xKTaO(3) and La0.55Li0.35-xKxTiO3. The results were explained by considering the effects of lattice expansion, site percolation and local distortion of the lattice.

引用

页码：165 / 169

页数：5

共 15 条

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[Anonymous], 2018, INTRO PERCOLATION TH

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Belous A. G., 1987, Izv. Akad. Nauk SSSR, V23, P470

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