Analysis by High-Performance Liquid Chromatography Diode Array Detection Mass Spectrometry of Phenolic Compounds in Fruit of Eucalyptus globulus Cultivated in Algeria

被引：72

作者：

Boulekbache-Makhlouf, Lila ^{[2
]}

Meudec, Emmanuelle ^{[1
]}

Chibane, Mohamed ^{[2
]}

Mazauric, Jean-Paul ^{[1
]}

Slimani, Sakina ^{[2
]}

Henry, Max ^{[3
]}

Cheynier, Veronique ^{[1
]}

Madani, Khodir ^{[2
]}

机构：

[1] INRA, UMR Sci Oenol 1083, F-34060 Montpellier, France

[2] A Mira Univ, Fac Nat & Life Sci, Lab 3Bs, Bejaia 06000, Algeria

[3] Nancy Univ, CNRS, UMR 7565, F-540001 Nancy, France

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 2010年 / 58卷 / 24期

关键词：

Eucalyptus globulus fruit; phenolic compounds; Sephadex LH-20 column; HPLC-DAD; HPLC-ESI-MS; HYDROLYZABLE TANNINS; ANTIOXIDANT ACTIVITY; E-RUDIS; LEAVES; POLYPHENOLS; IDENTIFICATION; ACID; GLYCOSIDES; PLANTS; PROANTHOCYANIDINS;

D O I：

10.1021/jf1029509

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

A method based on high-performance liquid chromatography coupled with diode array detection and electrospray ionization mass spectrometry (HPLC-DAD-ESI-MS) following fractionation by chromatography on a Sephadex LH-20 column has been developed to determine the phenolic composition of fruit of Eucalyptus globulus growing in Algeria. The presence of 18 gallotannins, 26 ellagitannins, and 2 flavonols was established. Tentative identification is provided for these compounds on the basis of UV-visible spectra and mass spectrometry data. Most compounds described in this study have not previously detected in fruit of E. globulus. Moreover, this is the first report of methyl digalloyl diglucose, 3,3'-O-dimethylellagic acid 4-O-beta-glucopyranoside, ellagic acid hexose, methyl ellagic acid pentose, methyltetragalloylglucose, and valoneic acid isomers (sanguisorbic, flavogallic acid dilactone) in the genus Eucalyptus.

引用

页码：12615 / 12624

页数：10

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