Synthesis and characterization of metal complexes with ampicillin

被引：28

作者：

Bravo, A

Anacona, JR

机构：

[1] Univ Oriente, Dept Quim, Cumana, Venezuela

[2] Univ Oriente, Dept Bioanal, Cumana, Venezuela

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1998年 / 44卷 / 1-2期

关键词：

ampicillin; cobalt(II); nickel(II); copper(II); zinc(II); cadmium(II);

D O I：

10.1080/00958979808022891

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction, in water, of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) ions with sodium ampicillinate at room temperature has allowed isolation;of dimers with the following general formula [M(amp)Cl](2) x nH(2)O (n = 1.5-3.2). The complexes were characterized by elemental analyses, conductivity measurements, magnetic susceptibilities and spectroscopic methods (IR, Raman, EPR and UV-Visible). A dinuclear structure based on octahedrally coordinated metal ions is proposed.

引用

页码：173 / 182

页数：10

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