Absolute configuration of (S)-(+)-[(benzyloxymethyl)(tert-butyl)methylsilyl] methyl ketone

被引：4

作者：

Bratovanov, S

Linden, A

Bienz, S

机构：

[1] Organisch-chemisches Institut, Universität Zürich, CH-8057 Zürich

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195014338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The absolute configuration of the title compound was confirmed by an X-ray crystal structure analysis of (R)-(+)-[(benzyloxymethyl)(tert-butyl)methylsilyl] methyl ketone 2,4,6-triisopropylphenylsulfonylhydrazone, C30H48N2O3SSi, reported herein. The asymmetric unit of the hydrazone contains two molecules which are linked by intermolecular hydrogen bonds.

引用

页码：1045 / 1047

页数：3

共 11 条

[1] CHIRAL ACYLSILANES IN ORGANIC-SYNTHESIS - DIASTEREOSELECTIVE 1,2-ADDITIONS TO RACEMIC ALKOXYMETHYL-SUBSTITUTED ACYLSILANES [J].