Electronic and magnetic properties of bimetallic ytterbocene complexes: The impact of bridging ligand geometry

被引：18

作者：

Carlson, Christin N. ^{[1
]}

Veauthier, Jacqueline M. ^{[1
]}

John, Kevin D. ^{[1
]}

Morris, David E. ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2008年 / 14卷 / 02期

关键词：

magnetic properties; metallocenes; UV/Vis spectroscopy; ytterbium;

D O I：

10.1002/chem.200700986

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bimetallic ytterbocene complexes with bridging N-heterocylic ligands have been studied extensively in recent years due to their potential applications ranging from molecular wires to single-molecule magnets. Herein, we review our recent results for a series of ytterbocene polypyridyl bimetallic complexes to highlight the versatility and tunability of these systems based on simple changes in bridging ligand geometry. Our work has involved structural, electrochemical, optical, and magnetic measurements with the goal of better understanding the electronic and magnetic communication between the two ytterbium metal centers in this new class of bimetallics.

引用

页码：422 / 431

页数：10

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