Some structure and magnetic effects of Ga incorporation on α-FeOOH

被引:20
作者
dos Santos, CA
Horbe, AMC
Barcellos, CMO
da Cunha, JBM
机构
[1] UFRGS, Inst Fis, BR-91501970 Porto Alegre, RS, Brazil
[2] Fundacao Univ Amazonas, Dept Geociencias, Manaus, Amazonas, Brazil
关键词
chemical synthesis; X-ray scattering; exchange and superexchange; nuclear resonances;
D O I
10.1016/S0038-1098(01)00147-8
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The effects of Ga incorporation on goethite were investigated by using X-ray diffractometry (XRD), particle-induced X-ray emission (PIXE), susceptibility measurements and Mossbauer spectroscopy (MS). Samples GaxFe1-xOOH were prepared with x = 0.00, 0.01, 0.03, 0.05, 0.10, 0.35 and 0.70. All the samples are single-phase and an accurate observation of the structure refinement procedure makes clear the sample-dependent structural behaviour. A model is proposed in which the main effect of Ga incorporation is to reduce the crystallite dimensions. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:449 / 452
页数:4
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