A three-dimensional metal-organic framework with an unprecedented octahedral building unit

被引：73

作者：

Livage, C

Guillou, N

Chaigneau, J

Rabu, P

Drillon, M

Férey, G

机构：

[1] Univ Versailles, CNRS, UMR 8637, Inst Lavoisier, F-78035 Versailles, France

[2] CNRS, UMR 7504, Inst Phys Chim Mat Strasbourg, F-67037 Strasbourg, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 40期

关键词：

carboxylate ligands; cobalt; metal-organic frameworks; solvothermal synthesis; supramolecular chemistry;

D O I：

10.1002/anie.200502185

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unusual octahedral hexamers built up from triangular, corner-linked cobalt trimers (see figure), form the basis of a novel three-dimensional cobalt isophthalate obtained by a solvothermal route. This structure provides a new example of the concept of scale chemistry, in which an {Na6Co 6O26} super octahedron" is connected in a classical ReO3 architecture. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA."

引用

页码：6488 / 6491

页数：4

共 43 条

[1]

[Anonymous], 2004, ANGEW CHEM, V116, P6445

[2] Synthetic and structural studies of cobalt-pivalate complexes [J].