Pt/C doped by MoOx as the electrocatalyst for oxygen reduction and methanol oxidation

被引：63

作者：

Elezovic, N. R. ^{[4
]}

Babic, B. M. ^{[3
]}

Radmilovic, V. R. ^{[2
]}

Gojkovic, S. Lj. ^{[1
]}

Krstajic, N. V. ^{[1
]}

Vracar, Lj. M. ^{[1
]}

机构：

[1] Univ Belgrade, Fac Technol & Met, YU-11001 Belgrade, Serbia

[2] LBLN Univ Calif Berkeley, Natl Ctr Electron Microscopy, Berkeley, CA USA

[3] Vinca Inst Nucl Sci, Belgrade, Serbia

[4] Univ Belgrade, Ctr Multidisciplinary Studies, YU-11001 Belgrade, Serbia

来源：

JOURNAL OF POWER SOURCES | 2008年 / 175卷 / 01期

关键词：

methanol oxidation; oxygen reduction; platinum; molybdenum oxides; TEM;

D O I：

10.1016/j.jpowsour.2007.09.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of methanol and reduction of oxygen were studied on MoOx-Pt/C nano-catalysts prepared by the polyole method combined by MoOx post-deposition. The catalysts were characterized by TEM and EDX. The presented composition of the electrode is very similar to the nominal ones and post-deposited MoOx species block only a small fraction of the active Pt particle surface area. MoOx deposition on the carbon support can be ruled out from the EDX results and the low mobility of these oxides at corresponding conditions. The electrode catalytic activity in the electrooxidation of methanol and the reduction of oxygen was studied by steady-state voltammetry and cyclic voltammetry. MoOx-Pt/C catalyst exhibits higher catalytic activity than Pt/C for the oxygen reduction. The catalytic effect in oxidation of methanol is achieved only under potentiodynamic conditions, when poisoning species have no enough time to develop fully. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：250 / 255

页数：6

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