Silylation of micro-, meso- and non-porous oxides: a review

被引：171

作者：

Impens, NREN ^{[1
]}

van der Voort, P ^{[1
]}

Vansant, EF ^{[1
]}

机构：

[1] Univ Instelling Antwerp, Dept Chem, Inorgan Chem Lab, B-2610 Wilrijk, Antwerp, Belgium

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 1999年 / 28卷 / 02期

关键词：

H-mordenite; mesoporous silica; non-porous silica; silylation;

D O I：

10.1016/S1387-1811(98)00239-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Changing the surface characteristics of silicon or mixed Si-Al oxides has created new prospects in both catalysis and separation technology. This review presents the surface modification of these materials by silylation over a wide range of pore sizes. The influence on the porosity, the adsorption characteristics and thermodynamic background of these modifications are summarised. The reaction mechanisms are reviewed for a wide range of silylation reagents. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：217 / 232

页数：16

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