Upconversion luminescence of Y3Al5O12 (YAG):Yb3+, Tm3+ nanocrystals

被引:37
作者
Liu, M.
Wang, S. W. [1 ]
Zhang, J.
An, L. Q.
Chen, L. D.
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
[2] Acad Sinica, Grad Sch Sci, Beijing 100039, Peoples R China
关键词
upconversion luminescence; YAG; Yb3+; Tm3+; nanocrystal;
D O I
10.1016/j.optmat.2006.11.060
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
YAG:Tm-3 divided by. and YAG:Yb3+, Tm3+ nanocrystals were synthesized by a co-precipitation method using ammonium hydrogen carbonate as precipitator. Pure nanocrystals with a crystallite size of 40 nm were obtained after the precipitates were calcined at 800 degrees C. YAG:Tm3+ and YAG:Yb-3 divided by, Tm-3 divided by powder compacts were excited by 796 and 940 nm, respectively. No upconversion emissions were observed either in YAG:Tm-3 divided by and YAG:Yb-3 divided by, T3+ nanocrystals excited at 796 nm or in YAG:Tm3+ nanocrystals excited at 940 nm. However, the blue emission of YAG:Yb-3 divided by, TM3+ nanocrystals excited by 940 nm was strong enough to be seen by the naked eyes. The emission intensity of this material was also influenced by Yb3+ concentration as well as the calcination temperature. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:370 / 374
页数:5
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