Dichloro(2,2′-diamino-4,4′-bi-1,3-thiazole-N3,N3′)copper(II)

被引：29

作者：

Liu, JG

Nie, JJ

Xu, DJ ^{[1
]}

Xu, YZ

Wu, JY

Chiang, MY

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

[2] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 80424, Taiwan

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2001年 / 57卷 / 57期

关键词：

D O I：

10.1107/S0108270100020163

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, [CuCl2(C6H6N4S2)], has a flattened tetrahedral coordination. The Cu-II atom is located on a twofold rotation axis and is coordinated by two N atoms from a chelating 2,2'-diamino-4,4'-bi-1,3-thiazole ligand and by two Cl atoms. Intramolecular hydrogen bonding exists between the amino groups of the 2,2'-diamino-4,4'-bi-1,3-thiazole ligand and the Cl atoms. The intermolecular separation of 3.425 (1) Angstrom between parallel bithiazole rings suggests there is a pi-pi interaction between them.

引用

页码：354 / 355

页数：2

共 17 条

[1] 1,4-DIMETHYL-1,4-DIAZONIABICYCLO[2.2.2]OCTANE OCTACHLOROTRICUPRATE(II) [J].