Improved designs of metal-organic frameworks for hydrogen storage

被引:205
作者
Han, Sang Soo [1 ]
Deng, Wei-Qiao [1 ]
Goddard, William A., III [1 ]
机构
[1] Nanyang Technol Univ, Singapore, Singapore
关键词
beryllium; hydrogen storage; magnesium; metal-organic frameworks; zinc;
D O I
10.1002/anie.200700303
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Quick on the uptake: The metal-organic framework Mg-MOF-C30 (see picture) contains Mg4O(CO2)6 building units (pink) and aromatic organic linkers containing 30 carbon atoms (teal). This material leads to 8.08 wt% H2 uptake at 77 K and 20 bar, the highest among investigated MOF structures. (Figure Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6289 / 6292
页数:4
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