3-aryl-4-hydroxycyclobut-3-ene-1,2-diones as sensitizers for TiO2 solar cell

被引:16
作者
Matsui, M [1 ]
Nagasaka, K [1 ]
Tokunaga, S [1 ]
Funabiki, K [1 ]
Yoshida, T [1 ]
Minoura, H [1 ]
机构
[1] Gifu Univ, Fac Engn, Dept Mat Sci & Technol, Gifu 5011193, Japan
关键词
dye-sensitized solar cell; TiO2; semisquaric acids; cyclic voltammetry; solar-light-to-electricity conversion efficiency; incident photon-to-current efficiency;
D O I
10.1016/S0143-7208(03)00067-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A series of 3-aryl-4-hydroxycyclobut-3-ene-1,2-diones were synthesized and examined as sensitizers for a TiO2 solar cell. The compounds showed strong affinity for TiO2 and the fluorescence intensity and self-assembly of the 3-aryl-4hydroxvcyclobut-3-ene-1,2-diones on the TiO2 surface were important factors in enhancing the solar-light-to-electricity conversion efficiency. The highest efficiency of 0.96% was observed for 3-[4-(didodecylamino)phenyl]-4-hydroxycyclobut-3-ene-1,2-dione. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:219 / 226
页数:8
相关论文
共 12 条
[1]  
ARAKAWA Y, 2001, NEW TECHNOLOGY DYES
[2]   REACTIONS OF SQUARIC ACID AND SOME DERIVATIVES WITH THIONYL CHLORIDE/N,N,-DIMETHYLFORMAMIDE [J].
DESELMS, RC ;
FOX, CJ ;
RIORDAN, RC .
TETRAHEDRON LETTERS, 1970, (10) :781-+
[3]  
FUJI FILM, 2000, Patent No. 2000058140
[4]  
FUJI FILM, 2000, Patent No. 2000251958
[5]  
Gratzel M, 2001, NATURE, P414
[6]   A coumarin-derivative dye sensitized nanocrystalline TiO2 solar cell having a high solar-energy conversion efficiency up to 5.6% [J].
Hara, K ;
Sayama, K ;
Ohga, Y ;
Shinpo, A ;
Suga, S ;
Arakawa, H .
CHEMICAL COMMUNICATIONS, 2001, (06) :569-570
[7]  
KEIL D, 1995, LIEBIGS ANN, P979
[8]   Fluorescent ligands for optical sensing of alcohols: Synthesis and characterisation of p-N,N-dialkylamino-trifluoroacetylstilbenes [J].
Mohr, GJ ;
Lehmann, F ;
Grummt, UW ;
SpichigerKeller, UE .
ANALYTICA CHIMICA ACTA, 1997, 344 (03) :215-225
[9]   A LOW-COST, HIGH-EFFICIENCY SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS [J].
OREGAN, B ;
GRATZEL, M .
NATURE, 1991, 353 (6346) :737-740
[10]   Photosensitization of a porous TiO2 electrode with merocyanine dyes containing a carboxyl group and a long alkyl chain [J].
Sayama, K ;
Hara, K ;
Mori, N ;
Satsuki, M ;
Suga, S ;
Tsukagoshi, S ;
Abe, Y ;
Sugihara, H ;
Arakawa, H .
CHEMICAL COMMUNICATIONS, 2000, (13) :1173-1174