A study of the ionic conductivity of lithium triflate compatible electrolyte gels with electrochromic systems

被引：3

作者：

Delacote, S

Lemordant, D

Topart, P

Bosser, G

机构：

[1] UFR Sci & Tech, PIMIR, F-37200 Tours, France

[2] CEA, Dept Mat, F-37200 Monts, France

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1998年 / 95卷 / 06期

关键词：

photopolymerized gel electrolytes; electrochromic systems;

D O I：

10.1051/jcp:1998329

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Gelified electrolytes have been realised by photopolymerisation of tetra(ethyleneglycol)diacrylate (TEG), The plasticiser is a ternary solvent composed of ethylelenecarbonate (EC), propylenecarbonate (PC) and 2-dimetoxyethylether (diglyme, DG), The conductivity is obtained by addition of lithium trifluoromethane sulfonate (triflate, TL), The composition of the plasticiser has been optimized in order to obtain a stable and optically transparent material in the temperature range: -25 to 100 degrees C and a conductivity of ca 5x10(-4) S cm(-1) at 20 degrees C, All these physical properties are compatible with the use of this material in electrochromic systems.

引用

页码：1563 / 1566

页数：4

共 8 条

[1] FLUIDITY AND CONDUCTANCE IN AQUEOUS-ELECTROLYTE SOLUTIONS - APPROACH FROM GLASSY STATE AND HIGH-CONCENTRATION LIMIT .1. CA(NO3)2 SOLUTIONS [J].