An investigation of the complexation behaviour of structurally modified tetrathiafulvalene derivatives with the electron deficient cyclophane cyclobis(paraquat-p-phenylene)

被引：27

作者：

Bryce, MR

Cooke, G

Duclairoir, FMA

Rotello, VM

机构：

[1] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland

[2] Univ Durham, Dept Chem, Durham DH1 3LE, England

[3] Univ Massachusetts, Dept Chem, Amherst, MA 01002 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 06期

关键词：

D O I：

10.1016/S0040-4039(00)02167-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This study has shown that easily oxidisable TTF units form charge-transfer (C-T) complexes with 7 which have the largest reported association constants to date. Replacing the sulfur of the TTF unit with selenium or extending the conjugated link between the two dithiole rings reduces the K-a of the complex relative to the parent derivative. (C) 2001 Published by Elsevier Science Ltd.

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页码：1143 / 1145

页数：3

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