Synthesis and properties of new chelating resin with a spacer containing α-nitroso-β-naphthol as the functional group

被引:8
作者
Akerkar, VG [1 ]
Karalkar, NB [1 ]
Sharma, RK [1 ]
Salunkhe, MM [1 ]
机构
[1] Inst Sci, Dept Chem, Mumbai 400032, India
关键词
alpha-nitroso-beta-naphthol; column operation; stepwise elution;
D O I
10.1016/S0039-9140(98)00017-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new chelating ion-exchange resin with a spacer CH2-NH-C6H4- based on a microreticular chloromethylated styrene-divinylbenzene copolymer containing alpha-nitroso-beta-naphthol as a functional group has been synthesized. The sorption characteristics for manganese(II), iron(III), cobalt(II), nickel(II), copper(II), and zinc(II) have been investigated over the pH range 1.0-7.0. The resin is highly stable in acidic and alkaline medium. Iron(III) and cobalt(II); copper(II) and iron(III) are separated very effectively in a column operation by stepwise elution. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1461 / 1467
页数:7
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