A simple and efficient procedure for oxidation of sulfides to sulfoxides on hydrated silica gel with ceric ammonium nitrate (CAN) in methylene chloride.

被引：42

作者：

Ali, MH ^{[1
]}

Leach, DR ^{[1
]}

Schmitz, CE ^{[1
]}

机构：

[1] SE Missouri State Univ, Dept Chem, Cape Girardeau, MO 63701 USA

来源：

SYNTHETIC COMMUNICATIONS | 1998年 / 28卷 / 16期

关键词：

D O I：

10.1080/00397919808004876

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple, fast and efficient procedure for oxidation of sulfides to the corresponding sulfoxides with CAN mediated by hydrated silica gel in methylene chloride has been developed. To our knowledge, this is the first example of oxidation of sulfides with CAN in a non-aqueous media.

引用

页码：2969 / 2981

页数：13

共 25 条

[1]

AKEMI T, 1996, CHEM PHARM BULL, V44, P703

[2]

Ali MH, 1997, SYNTHESIS-STUTTGART, P764

[3] SYNTHESIS OF SULFOXIDES BY PHASE-TRANSFER CATALYZED OXIDATION OF SULFIDES BY CERIUM(IV) AMMONIUM-NITRATE [J].

BACIOCCHI, E ;

PIERMATTEI, A ;

RUZZICONI, R .

SYNTHETIC COMMUNICATIONS, 1988, 18 (16-17) :2167-2171

[4] SYNTHESIS OF ARYL METHYL SULFOXIDES AND DETERMINATION OF THE CONJUGATIVE EFFECT OF THE METHYLSUFINYL GROUP [J].

BORDWELL, FG ;

BOUTAN, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (03) :717-722

[5] HIGHLY ENANTIOSELECTIVE OXIDATION OF SULFIDES MEDIATED BY A CHIRAL TITANIUM COMPLEX [J].

BRUNEL, JM ;

DITER, P ;

DUETSCH, M ;

KAGAN, HB .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (24) :8086-8088

[6] Tetrabutylammonium peroxydisulfate in organic synthesis .3. An efficient procedure for the selective oxidation of sulfides to sulfoxides by tetrabutylammonium peroxydisulfate [J].

Chen, F ;

Wan, JL ;

Guan, CS ;

Yang, JS ;

Zhang, H .

SYNTHETIC COMMUNICATIONS, 1996, 26 (02) :253-260

[7]

DRABOWICZ J, 1979, SYNTHESIS-STUTTGART, P39

[8]

DRABOWICZ J, 1990, SYNTHESIS-STUTTGART, P937

[9]

DRABOWICZ J, 1994, SYNTHESIS SULPHONES, pCH3

[10] SULFOXIDES FROM THIOETHERS AND MNO2-HCL [J].

FABRETTI, A ;

GHELFI, F ;

GRANDI, R ;

PAGNONI, UM .

SYNTHETIC COMMUNICATIONS, 1994, 24 (17) :2393-2398

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