The incorrectness of the temperature criterion

被引：16

作者：

Ortega, A

机构：

[1] Instituto de Ciencias de Materiales, Dpto. Quim. Inorg. (Univ. Sevilla), 41080, Sevilla

来源：

THERMOCHIMICA ACTA | 1996年 / 276卷

关键词：

kinetic parameters; temperature integral; temperature criterion; thermal decomposition; thermogravimetry;

D O I：

10.1016/0040-6031(95)02737-8

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The errors in the activation energy of solid-state reactions calculated using ''temperature criterion'' method have been calculated; errors in the kinetic parameters are strongly dependent on the kinetic law obeyed by the reaction. A theoretical explanation of this behaviour is given.

引用

收藏

页码：189 / 198

页数：10

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