All-solid-state lithium polymer secondary battery with LiNi0.5Mn1.5O4 by mixing of Li3PO4

被引:42
作者
Miyashiro, H
Seki, S
Kobayashi, Y
Ohno, Y
Mita, Y
Usami, A
机构
[1] Cent Res Inst Elect Power Ind, Mat Sci Res Lab, Tokyo 2018511, Japan
[2] Elect Power Engn Syst Co Ltd, Tokyo 2018511, Japan
关键词
all-solid-state lithium polymer secondary battery; solid polymer electrolyte; LiNi0.5Mn1.5O4; Li3PO4;
D O I
10.1016/j.elecom.2005.08.006
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
5 V-class all-solid-state lithium polymer secondary batteries were prepared by the mixing of solid inorganic electrolyte (SlE, Li3PO4) with LiNi0.5Mn1.5O4 powder. The discharge capacity exhibited >120 and >550 mWh g(-1) at the operation temperature of 333 K. We also prepared a lithium-metal-free battery by using copper current collector at the anode, and exhibit the similar discharge capacity. Our demonstration indicates the marked improvement in the energy density of lithium polymer batteries through a simple preparation, which leads to the manufacture of large-scaled batteries. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1083 / 1086
页数:4
相关论文
共 17 条
[1]   Study of the interface nickel/composite cathode of industrially made Li/V2O5 polymer (POE) batteries working at 90°C [J].
André, P ;
Deniard, P ;
Brec, R ;
Lascaud, S .
JOURNAL OF POWER SOURCES, 2002, 105 (01) :66-74
[2]  
Armand M. B., 1979, FAST ION TRANSPORT S
[3]   Lithium polymer battery development for electric vehicle application [J].
Baudry, P ;
Lascaud, S ;
Majastre, H ;
Bloch, D .
JOURNAL OF POWER SOURCES, 1997, 68 (02) :432-435
[4]   SOLID-SOLUTIONS BETWEEN OCTAHEDRAL AND TETRAHEDRAL OLIVINE TYPES IN LI-ZN-GERMANATES [J].
BAUR, WH .
INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1980, 16 (9-12) :525-527
[5]   Nanocomposite polymer electrolytes for lithium batteries [J].
Croce, F ;
Appetecchi, GB ;
Persi, L ;
Scrosati, B .
NATURE, 1998, 394 (6692) :456-458
[6]   5 V class all-solid-state composite lithium battery with Li3PO4 coated LiNi0.5Mn1.5O4 [J].
Kobayashi, Y ;
Miyashiro, H ;
Takei, K ;
Shigemura, H ;
Tabuchi, M ;
Kageyama, H ;
Iwahori, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (12) :A1577-A1582
[7]  
KOBAYASHI Y, IN PRESS J POWER SOU
[8]  
KOBAYASHI Y, IN PRESS J ELECTROCH
[9]   Liquid-free rechargeable Li polymer battery [J].
Matsui, S ;
Muranaga, T ;
Higobashi, H ;
Inoue, S ;
Sakai, T .
JOURNAL OF POWER SOURCES, 2001, 97-8 :772-774
[10]   High ionic conductivity of polyether-based network polymer electrolytes with hyperbranched side chains [J].
Nishimoto, A ;
Agehara, K ;
Furuya, N ;
Watanabe, T ;
Watanabe, M .
MACROMOLECULES, 1999, 32 (05) :1541-1548