A simple method for epoxidation of olefins using sodium chlorite as an oxidant without a catalyst

被引：47

作者：

Geng, XL ^{[1
]}

Wang, Z ^{[1
]}

Li, XQ ^{[1
]}

Zhang, C ^{[1
]}

机构：

[1] Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Res Inst Elementoorgan Chem, Tianjin 300072, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 23期

关键词：

D O I：

10.1021/jo0511400

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sodium chlorite has been demonstrated to be capable of epoxidizing a variety of olefins at 55-65 degrees C (oil bath). Chlorine dioxide is believed to be the pivotal epoxidizing agent in the reaction on the basis of the mechanistic studies.

引用

页码：9610 / 9613

页数：4

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