A novel and versatile methodology for functionalization of conjugated polymers. Transformation of poly(3-bromo-4-hexylthiophene) via palladium-catalyzed coupling chemistry

被引：66

作者：

Li, YN ^{[1
]}

Vamvounis, G ^{[1
]}

Yu, JF ^{[1
]}

Holdcroft, S ^{[1
]}

机构：

[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada

来源：

MACROMOLECULES | 2001年 / 34卷 / 10期

关键词：

D O I：

10.1021/ma010293w

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A methodology for functionalization of conjugated polymers and transformation of poly(3-bromo-4-hexylthiophene) via palladium-catalyzed coupling chemistry was analyzed using nuclear magnetic resonance (NMR) spectroscopy. The 4-hydrogen of poly(3-hexylthiophene) (P3HT) was susceptible to electrophilic substitution and can be quantitatively replaced with a halogen or nitro group. The results show that P3HT is efficiently functionalized using bromination and subsequent palladium-catalyzed cross-coupling reactions.

引用

页码：3130 / 3132

页数：3

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