Raman spectra of putrescine, spermidine and spermine polyamines and their N-deuterated and N-ionized derivatives

被引：27

作者：

da Costa, AMA ^{[1
]}

Marques, MPM

de Carvalho, LAEB

机构：

[1] Univ Coimbra, Unidade I&D Quim Fis Mol, P-3000 Coimbra, Portugal

[2] Univ Coimbra, Fac Sci & Technol, Dept Biochem, P-3000 Coimbra, Portugal

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 2003年 / 34卷 / 05期

关键词：

putrescine; spermidine; spermine; conformational analysis; polyamines;

D O I：

10.1002/jrs.1001

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The experimental and calculated Raman spectra of the N-hydrogenated and N-deuterated biogenic polyamines putrescine, spermidine and spermine and of their N-hydrogenated and N-deuterated hydrochloride salts in the 2000-3400 cm(-1) spectral region (at distinct temperatures) are reported and analysed. A complete assignment of the N-H, C-H and N-D stretching modes is carried out, in the light of both steric and hydrogen-bonding interactions on the conformational behaviour of these systems. Copyright (C) 2003 John Wiley Sons, Ltd.

引用

页码：357 / 366

页数：10

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