Vibrational spectra of nitric acid dihydrate (NAD)

被引:18
作者
Grothe, H
Myhre, CEL
Tizek, H
机构
[1] Vienna Tech Univ, Inst Mat Chem, A-1210 Vienna, Austria
[2] Univ Oslo, Dept Chem, N-0315 Oslo, Norway
基金
奥地利科学基金会;
关键词
nitric acid dihydrate; X-ray diffraction; Raman spectroscopy; IR spectroscopy;
D O I
10.1016/j.vibspec.2003.05.001
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Nitric acid dihydrate (NAD), which may be an important constituent in polar stratospheric clouds, has been investigated by infrared and Raman spectroscopy. Spectral changes, upon variation in temperature and concentration, have been analysed in detail and interpreted as a phase change between a low- and a high-temperature modification. This interpretation was corroborated by the results of a previous X-ray diffraction (XRD) study of samples prepared under essentially the same conditions. The present FTIR spectra are compared to literature data. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:55 / 62
页数:8
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