Allyldiisopropylphenylsilane as a synthetic equivalent of 2-hydroxy-1,3-dipole. Stereoselective synthesis of cyclopentanols

被引：42

作者：

Akiyama, T ^{[1
]}

Hoshi, E ^{[1
]}

Fujiyoshi, S ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 14期

关键词：

D O I：

10.1039/a804118k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

ZrCl4-Promoted [3+2] cycloaddition of allyldiisopropylphenylsilane to alpha,beta-unsaturated ketones proceeds smoothly to afford silyl-substituted cyclopentanes highly stereoselectively. Oxidative cleavage of the carbon-silicon bond leads to stereoselective formation of cyclopentanols.

引用

页码：2121 / 2122

页数：2

共 31 条

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