Mo6+-doped Li[Ni(0.5+x)Mn(1.5-2x)Mox]O4 spinel materials for 5 V lithium secondary batteries prepared by ultrasonic spray pyrolysis

被引：31

作者：

Park, SH ^{[1
]}

Oh, SW

Myung, ST

Sun, YK

机构：

[1] Hanyang Univ, Dept Chem Engn, Ctr Informat & Commun Mat, Seoul 133791, South Korea

[2] VK Corp, Pyongtaek 450090, Kyonggi Do, South Korea

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2004年 / 7卷 / 11期

关键词：

D O I：

10.1149/1.1808114

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Molybdenum-doped spinel Li[Ni(0.5+x)Mn(1.5-2x)Mox]O-4 (0 <= x <= 0.1) materials were synthesized by an ultrasonic spray pyrolysis method. Well-ordered [111] direction (octahedron shape) morphology powders were obtained at molybdenum-doped spinel. The structural, electrochemical, morphological properties, and thermal stability of the powders were characterized by X-ray diffraction, galvanostatic charge/discharge testing, scanning electron microscopy, and differential scanning calorimetry, respectively. The molybdenum doping spinel has a high discharge capacity, excellent capacity retention, rate capability, and thermal stability. (C) 2004 The Electrochemical Society.

引用

页码：A451 / A454

页数：4

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