Direct voltammetric evidence for a reducing agent generated from the electrochemical oxidation of tripropylamine for electrochemiluminescence of ruthenium tris(bipyridine) complexes?

被引：12

作者：

Zhou, M

Heinze, J

Borgwarth, K

Grover, CP

机构：

[1] Natl Res Council Canada, Inst Natl Measurement Stand, Ottawa, ON K1A 0R6, Canada

[2] Univ Freiburg, Inst Phys Chem, D-79104 Freiburg, Germany

来源：

CHEMPHYSCHEM | 2003年 / 4卷 / 11期

关键词：

amines; luminescence; electrochemistry; tripropylamine;

D O I：

10.1002/cphc.200300875

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical lighting? A redox-active substance was found to be a product of the electrochemical oxidation of tripropylamine (see picture). With regard to the strong reducing ability of the reduced form of the substance, the chemical nature of the species is discussed with respect to the tripropylamine free radical, which is believed to participate in the formation of the luminescent excited state of [Ru(bpy)3]2+ in both acetonitrile and aqueous solutions. The findings may help understand the complicated anodic oxidation mechanism of trialkylamines, which is crucial to the generation of electrochemiluminescence of [Ru(bpy)3] 2+.

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收藏

页码：1241 / 1243

页数：3

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