Cubane tetrameric complexes of copper(I) chloride and bromide with triphenyl phosphite

被引：22

作者：

Pike, RD ^{[1
]}

Starnes, WH

Carpenter, GB

机构：

[1] Coll William & Mary, Dept Chem, Williamsburg, VA 23187 USA

[2] Brown Univ, Dept Chem, Providence, RI 02912 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198012451

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of tetra-mu(3)-chloro-tetrakis[(triphenyl phosphite-P)copper(I)], [Cu4Cl4(C18H15O3P)(4)], and tetra-mu(3)-bromo-tetrakis [(triphenyl phosphite-P)copper(I)], [Cu4Br4(C18H15O3P)(4)], are described. Both have distorted 'cubane' Cu4X4 cores. Distortion of the cubane structure is reflected in X-Cu-X angles > 90 degrees and Cu-X-Cu angles < 90 degrees, and is more pronounced in the bromide complex.

引用

页码：162 / 165

页数：4

共 22 条

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