Aggregates from cetyltrimethylammoniumhydroxynaphthalene carboxylate (CTAHNC): A light scattering study

被引:28
作者
Hassan, PA
Narayanan, J
Menon, SVG
Salkar, RA
Samant, SD
Manohar, C
机构
[1] BHABHA ATOM RES CTR,DIV CHEM,BOMBAY 400085,MAHARASHTRA,INDIA
[2] R J COLL,DEPT PHYS,BOMBAY 400086,MAHARASHTRA,INDIA
[3] BHABHA ATOM RES CTR,DIV THEORET PHYS,BOMBAY 400085,MAHARASHTRA,INDIA
[4] UNIV BOMBAY,DEPT CHEM TECHNOL,DEPT CHEM,BOMBAY 400019,MAHARASHTRA,INDIA
关键词
aggregates; bending rigidity; cetyltrimethylammoniumhydroxynaphthalene; light scattering; vesicles;
D O I
10.1016/0927-7757(96)03675-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A light scattering study of cetyltrimethylammoniumhydroxynaphthalene carboxylate (CTAHNC) is presented. In the concentration range studied (0.07-0.6 mM) the structure of the micellar aggregate is likely to be vesicles of size similar to 100 nm. HNC- is expected to act as a co-surfactant which reduces the bending rigidity, k(c), of the bilayer membrane leading to a rough and undulating surface for the vesicles. The fractal dimension d approximate to 2-2.6, which fits the light scattering data, supports this view. A scanning electron micrograph at a higher concentration indicates that the aggregates are vesicles.
引用
收藏
页码:89 / 94
页数:6
相关论文
共 28 条
[1]  
ANGEL M, 1984, PROG COLL POL SCI S, V69, P12
[2]  
APPELL J, 1992, J PHYS II, V2, P1045
[3]   POLYMER-LIKE BEHAVIOR OF GIANT MICELLES [J].
APPELL, J ;
PORTE, G .
EUROPHYSICS LETTERS, 1990, 12 (02) :185-190
[4]   CLOUD POINT PHENOMENA IN THE PHASE-BEHAVIOR OF ALKYL POLYGLUCOSIDES IN WATER [J].
BALZER, D .
LANGMUIR, 1993, 9 (12) :3375-3384
[5]   THREADLIKE MICELLES FROM CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS SODIUM NAPHTHALENESULFONATE SOLUTIONS STUDIED BY STATIC AND DYNAMIC LIGHT-SCATTERING [J].
BROWN, W ;
JOHANSSON, K ;
ALMGREN, M .
JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (15) :5888-5894
[6]   DYNAMICS OF LIVING POLYMERS AND FLEXIBLE SURFACTANT MICELLES - SCALING LAWS FOR DILUTION [J].
CATES, ME .
JOURNAL DE PHYSIQUE, 1988, 49 (09) :1593-1600
[7]   NONLINEAR VISCOELASTICITY OF WORMLIKE MICELLES (AND OTHER REVERSIBLY BREAKABLE POLYMERS) [J].
CATES, ME .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (01) :371-375
[8]  
FENDLER JH, 1982, MEMBRANE MIMETIC CHE
[9]   SCALING FUNCTION FOR 2-POINT CORRELATIONS .1. EXPANSION NEAR 4 DIMENSIONS [J].
FISHER, ME ;
AHARONY, A .
PHYSICAL REVIEW B, 1974, 10 (07) :2818-2833
[10]   VISCOELASTICITY IN HIGHLY DILUTE AQUEOUS-SOLUTIONS OF PURE CATIONIC DETERGENTS [J].
GRAVSHOLT, S .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1976, 57 (03) :575-577