Na2SO3/SOCl2, an efficient reagent for the dehydration of aldoximes to nitriles

被引：12

作者：

Kiasat, AR ^{[1
]}

Kazemi, F ^{[1
]}

Khosravian, F ^{[1
]}

机构：

[1] Shahid Chamran Univ, Coll Sci, Dept Chem, Ahvaz, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2003年 / 178卷 / 06期

关键词：

aldoxime; nitrile; solid state; thionyl chloride;

D O I：

10.1080/10426500307896

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aldoximes undergo rapid dehydration with sodium sulfite, thionyl chloride, under mild reaction condition to afford nitriles in excellent isolated yields. Dehydration reactions were performed in solvent and under solvent free conditions.

引用

页码：1377 / 1383

页数：7

共 28 条

[1] CHEMISTRY OF PHOSGENE [J].

BABAD, H ;

ZEILER, AG .

CHEMICAL REVIEWS, 1973, 73 (01) :75-91

[2] ENVIROCAT EPZG(R), A NEW CATALYST FOR THE CONVERSION OF ALDOXIMES INTO NITRILES [J].

BANDGAR, BP ;

JAGTAP, SR ;

GHODESHWAR, SB ;

WADGAONKAR, PP .

SYNTHETIC COMMUNICATIONS, 1995, 25 (19) :2993-2998

[3] Microwave activation in organic synthesis:: Natural Indian clay, EPIC® EPZG® and EPZ10® as novel heterogenous catalysts for rapid synthesis of nitriles from aldoximes in absence of solvent [J].

Bandgar, BP ;

Sadavarte, VS ;

Sabu, KR .

SYNTHETIC COMMUNICATIONS, 1999, 29 (19) :3409-3413

[4]

Das B, 2000, SYNLETT, P1599

[5]

*FLUK, 1999, FLUK HDB FIN CHEM

[6]

HIASHI F, 1986, J POLYM SCI A, P701

[7]

KAMAL A, 2002, SYNTHETIC COMMUN, V4, P625

[8] Efficient conversion of oxiranes to thiiranes with thiourea catalyzed with ruthenium trichloride and alumina [J].

Kazemi, F ;

Kiasat, AR ;

Ebrahimi, S .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2001, 176 :135-140

[9] Reduction of carbonyl compounds to the corresponding alcohols with isopropanol on dehydrated alumina under microwave irradiation [J].

Kazemi, F ;

Kiasat, AR .

SYNTHETIC COMMUNICATIONS, 2002, 32 (14) :2255-2260

[10] LiBF4:: A mild and efficient catalyst for the tetrahydropyranylation of alcohols and their detetrahydropyranylation [J].

Kazemi, F ;

Kiasat, AR ;

Ebrahimi, S .

SYNTHETIC COMMUNICATIONS, 2002, 32 (16) :2483-2487

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