Physical gelation of polar aprotic solvents induced by hydrogen bonding modulation of polymeric molecules

被引:10
作者
Ka, Duyoun [1 ]
Seo, Myungeun [1 ]
Choi, Hyungsam [1 ]
Kim, Eun Hee [2 ]
Kim, Sang Youl [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[2] Korea Basic Sci Inst, Div Magnet Resonance, Cheongwon 363883, Chungbuk, South Korea
关键词
ORGANIC LIQUIDS; CHEMISTRY; GELATORS; SPECTRA; GEL;
D O I
10.1039/c0cc00994f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poly(aryl ether amide) containing o-nitroanilide forms a physical gel in polar aprotic solvents by solvent-induced change of hydrogen bonding modes, in which hydrogen bonding acceptor solvent molecules break intramolecular hydrogen bonding of o-nitroanilide and induce intermolecular hydrogen bonding.
引用
收藏
页码:5722 / 5724
页数:3
相关论文
共 40 条
[1]  
ANDREWS BD, 1969, TETRAHEDRON LETT, P1859
[2]   On the high viscosity of aqueous solution of lysozyme induced by some organic solvents [J].
Areas, EPG ;
Areas, JAG ;
Hamburger, J ;
Peticolas, WL ;
Santos, PS .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 180 (02) :578-589
[3]   Calixarene-based multivalent ligands [J].
Baldini, L. ;
Casnati, A. ;
Sansone, F. ;
Ungaro, R. .
CHEMICAL SOCIETY REVIEWS, 2007, 36 (02) :254-266
[4]   Thixotropy - A review [J].
Barnes, HA .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 1997, 70 (1-2) :1-33
[5]  
BARNES HA, 1989, INTRO RHEOLOGY, V3, pCH2
[6]   SELECTIVE DESHIELDING OF AROMATIC PROTONS IN SOME ORTHO-SUBSTITUTED ACETANILIDES [J].
BARTELSKEITH, JR ;
CIECIUCH, RF .
CANADIAN JOURNAL OF CHEMISTRY-BACK YEAR, 1968, 46 (15) :2593-+
[7]   Meta-activated nucleophilic aromatic substitution reaction: Poly(biphenylene oxide)s with trifluoromethyl pendent groups via nitro displacement [J].
Chung, IS ;
Kim, SY .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (44) :11071-11072
[8]   Water gelation by small organic molecules [J].
Estroff, LA ;
Hamilton, AD .
CHEMICAL REVIEWS, 2004, 104 (03) :1201-1217
[9]   Stimuli-reponsive polymers and their bioconjugates [J].
Gil, ES ;
Hudson, SM .
PROGRESS IN POLYMER SCIENCE, 2004, 29 (12) :1173-1222
[10]   DOSY NMR experiments as a tool for the analysis of constitutional and motional dynamic processes: Implementation for the driven evolution of dynamic combinatorial libraries of helical strands [J].
Giuseppone, Nicolas ;
Schmitt, Jean-Louis ;
Allouche, Lionel ;
Lehn, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (12) :2235-2239