Reinvestigation of the reaction of strontium and barium with iodobenzene and molecular structure of the heavy Grignard reagent [((thf)2BaPh2)4 • (thf)BaO] with an oxygen-centered square Ba5 pyramid

被引：27

作者：

Langer, Jens ^{[1
]}

Gaertner, Martin ^{[1
]}

Fischer, Reinald ^{[1
]}

Goerls, Helmar ^{[1
]}

Westerhausen, Matthias ^{[1
]}

机构：

[1] Univ Jena, Inst Inorgan & Analyt Chem, D-07743 Jena, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 09期

关键词：

strontium; barium; phenylstrontium iodide; phenylbarium iodide; diphenylbarium;

D O I：

10.1016/j.inoche.2007.05.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The direct synthesis of activated strontium and barium with iodobenzene in THF yields the corresponding THF complexes of phenylstrontium and phenylbarium iodide, respectively, which dismutate into the homoleptic compounds MPh2 and MI2. Already at low temperatures ether cleavage reactions take place and from this reaction, the oxygen-centered cage [((thf)(2)BaPh2)(4) center dot(thf)BaO] was isolated and its molecular structure determined. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1001 / 1004

页数：4

共 43 条

[1]

Alexander JS, 2002, EUR J INORG CHEM, P2761

[2]

[Anonymous], ADV ORGANOMET CHEM

[3] Adducts of carbenes with group II and XII metallocenes [J].