water;
ammonia;
H/D exchange;
sputtering;
time-of-flight secondary ion mass spectrometry;
D O I:
10.1016/j.nimb.2005.03.036
中图分类号:
TH7 [仪器、仪表];
学科分类号:
0804 ;
080401 ;
081102 ;
摘要:
The influence of the ion bombardment on the surface properties of water-ice films has been investigated. The films are irradiated with 1.5 keV He+ ions and analyzed sequentially on the basis of time-of-flight secondary-ion mass spectrometry (TOF-SIMS). In order to minimize any temperature-induced effects, the measurements were made at 15 K. The damage of the films, as estimated from the H/D exchange between NH3 and the D2O ice and the intermixing of NH3 with the (H2O)-O-18 ice, is recognized at the fluence above 2 x 10(14) ions/cm(2). The sputtering yield of the D2O ice is determined as 0.9 +/- 0.2 molecules per incoming He+ ion. The temperature-programmed TOF-SIMS analysis of the water-ice films has been completed within the fluence of 5.8 x 10(12) ions/cm(2), so that no appreciable damage of the film should be induced during the measurement. (c) 2005 Elsevier B.V. All rights reserved.