Influence of helium-ion bombardment on the surface properties of pure and ammonia-adsorbed water thin films

被引:8
作者
Kondo, M
Shibata, T
Kawanowa, H
Gotoh, Y
Souda, R
机构
[1] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan
[2] Sci Univ Tokyo, Dept Mat Sci & Technol, Noda, Chiba 2788510, Japan
关键词
water; ammonia; H/D exchange; sputtering; time-of-flight secondary ion mass spectrometry;
D O I
10.1016/j.nimb.2005.03.036
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
The influence of the ion bombardment on the surface properties of water-ice films has been investigated. The films are irradiated with 1.5 keV He+ ions and analyzed sequentially on the basis of time-of-flight secondary-ion mass spectrometry (TOF-SIMS). In order to minimize any temperature-induced effects, the measurements were made at 15 K. The damage of the films, as estimated from the H/D exchange between NH3 and the D2O ice and the intermixing of NH3 with the (H2O)-O-18 ice, is recognized at the fluence above 2 x 10(14) ions/cm(2). The sputtering yield of the D2O ice is determined as 0.9 +/- 0.2 molecules per incoming He+ ion. The temperature-programmed TOF-SIMS analysis of the water-ice films has been completed within the fluence of 5.8 x 10(12) ions/cm(2), so that no appreciable damage of the film should be induced during the measurement. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:140 / 145
页数:6
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