Synthesis by neutral surfactant assembly of ordered mesoporous organic-inorganic hybrid materials incorporating phosphorus centres

被引：29

作者：

Corriu, RJP ^{[1
]}

Mehdi, A ^{[1
]}

Reyé, C ^{[1
]}

机构：

[1] Univ Montpellier 2, Lab Chim Mol & Org Solide, UMR 5637, F-34095 Montpellier 5, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1999年 / 2卷 / 01期

关键词：

sol-gel; surfactant; phosphine; mesopore;

D O I：

10.1016/S1387-1609(99)80036-X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The co-condensation of tetraethoxysilane (TEOS) and organotrialkoxysilane R'Si(OEt)(3) (R' group containing a phosphorus acorn) in the presence of a neutral surfactant (n-C16H33NH2) template provides ordered mesoporous hybrid materials. We show that further chemical reactions (sulfuration and quaternization) at phosphorus centres do not disrupt. the ordered structure and the textural characteristics of the materials. (C) Academie des sciences/Elsevier, Paris.

引用

页码：35 / 39

页数：5

共 23 条

[1] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES
BECK, JS
VARTULI, JC
ROTH, WJ
LEONOWICZ, ME
KRESGE, CT
SCHMITT, KD
CHU, CTW
OLSON, DH
SHEPPARD, EW
MCCULLEN, SB
HIGGINS, JB
SCHLENKER, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10834 - 10843
[2] Preparation and characterization of new organic-inorganic hybrid materials incorporating phosphorus centres
Bezombes, JP
Chuit, C
Corriu, RJP
Reye, C
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (08) : 1749 - 1759
[3] Brunel D, 1995, STUD SURF SCI CATAL, V97, P173
[4] Synthesis of hybrid inorganic-organic mesoporous silica by co-condensation of siloxane and organosiloxane precursors
Burkett, SL
Sims, SD
Mann, S
[J]. CHEMICAL COMMUNICATIONS, 1996, (11) : 1367 - 1368
[5] SELECTIVE PHOSPHINATION OF (3-CHLOROPROPYL)TRIETHOXYSILANE, A NEW ROUTE TO ALKOXYSILYL-SUBSTITUTED PHOSPHINES
CAPKA, M
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1977, 7 (04): : 347 - 354
[6] Monoglyceride synthesis by heterogeneous catalysis using MCM-41 type silicas functionalized with amino groups
Cauvel, A
Renard, G
Brunel, D
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (03) : 749 - 751
[7] CAUVEL A, 1996, AM I PHYS, V354, P477
[8] A new trend in metal-alkoxide chemistry: the elaboration of monophasic organic-inorganic hybrid materials
Corriu, R
[J]. POLYHEDRON, 1998, 17 (5-6) : 925 - 934
[9] Recent developments of molecular chemistry for sol-gel processes
Corriu, RJP
Leclercq, D
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (13-14): : 1420 - 1436
[10] Functionalized monolayers on ordered mesoporous supports
Feng, X
Fryxell, GE
Wang, LQ
Kim, AY
Liu, J
Kemner, KM
[J]. SCIENCE, 1997, 276 (5314) : 923 - 926

← 1 2 3 →