Hybrid inorganic-organic materials: a new family in condensed matter physics

被引:320
作者
Rao, C. N. R. [1 ]
Cheetham, A. K. [2 ]
Thirumurugan, A. [1 ]
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
[2] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
关键词
D O I
10.1088/0953-8984/20/8/083202
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We review some recent trends in an emerging field at the interface between classical inorganic and organic materials. Hybrid inorganic-organic framework materials are crystalline systems in which both inorganic and organic structural elements co-exist within a single phase. Much of the focus in this area during the last few years has been on porous hybrid frameworks, which are of interest for potential applications in catalysis, separations and sensors. The primary focus of our overview is on properties that traditionally lie in the domain of condensed matter physics: magnetism, optical, electronic and dielectric properties. We show that these materials exhibit a rich diversity of behavior in these areas and present some exciting opportunities for the physics community. We also present a short summary of some of the properties found in porous materials.
引用
收藏
页数:21
相关论文
共 110 条
[1]   CRYSTALLINE ZR(R-PO3)2 AND ZR(R-OPO3)2 COMPOUNDS (R=ORGANIC RADICAL) - NEW CLASS OF MATERIALS HAVING LAYERED STRUCTURE OF ZIRCONIUM-PHOSPHATE TYPE [J].
ALBERTI, G ;
COSTANTINO, U ;
ALLULLI, S ;
TOMASSINI, N .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1978, 40 (06) :1113-1117
[2]  
Bailar Jr J. C, 1964, PREPARATIVE INORGANI, V1, P1
[3]   Synthesis, structure determination and magnetic behaviour of the first porous hybrid oxyfluorinated vanado(III)carboxylate:: MIL-71 or VIII2(OH)2F2{O2C-C6H4-CO2}•H2O [J].
Barthelet, K ;
Adil, K ;
Millange, F ;
Serre, C ;
Riou, D ;
Férey, G .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (09) :2208-2212
[4]  
Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO
[5]  
2-Y
[6]   Synthesis, structure and magnetic properties of an amine-templated Mn2+ (S=5/2) sulfate with the Kagome structure [J].
Behera, J. N. ;
Rao, C. N. R. .
DALTON TRANSACTIONS, 2007, (06) :669-673
[7]   A Ni2+ (S=1) Kagome compound templated by 1,8-diazacubane [J].
Behera, J. N. ;
Rao, C. N. R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (29) :9334-9335
[8]   Design, chirality, and flexibility in nanoporous molecule-based materials [J].
Bradshaw, D ;
Claridge, JB ;
Cussen, EJ ;
Prior, TJ ;
Rosseinsky, MJ .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282
[9]  
Byrappa K., 2001, HDB HYDROTHERMAL TEC
[10]   There's room in the middle [J].
Cheetham, Anthony K. ;
Rao, C. N. R. .
SCIENCE, 2007, 318 (5847) :58-59