Two-dimensional aggregation of organogelators induced by biaxial hydrogen-bonding gives supramolecular nanosheets

被引:65
作者
Davis, Riju
Berger, Ruediger
Zentel, Rudolf
机构
[1] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany
[2] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
D O I
10.1002/adma.200701057
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanosheet gel structures are formed by a class of bis-acylurea organogelator molecules, which self-organize into regular 2D sheet morphologies having planar dimensions of several micrometers and thicknesses (ca. 2 nm) corresponding to their molecular lengths. The 2D self-assembly is a consequence of unique intermolecular biaxial hydrogen bonding.
引用
收藏
页码:3878 / +
页数:5
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