Interpreting and controlling the structures of six-coordinate copper(II) centres - When is a compression really a compression?

被引：110

作者：

Halcrow, MA ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

DALTON TRANSACTIONS | 2003年 / 23期

关键词：

D O I：

10.1039/b309242a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Many experimental observations of 'inverse' or 'quenched' Jahn-Teller effects in copper(II) compounds in fact reflect a normal Jahn-Teller-elongated configuration that is masked by structural disorder. On the other hand, a small number of copper(II) complexes are known that genuinely exhibit these unusual structures. It requires careful interpretation of spectroscopic and structural data to distinguish these two scenarios.

引用

页码：4375 / 4384

页数：10

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