Soft X-ray excited optical luminescence studies of gold(I) complex with diphosphine and 4,4′-bipyridyl ligands

被引：10

作者：

Kim, PSG

Brandys, MC

Hu, YF

Puddephatt, RJ

Sham, TK ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Univ Wisconsin, Ctr Synchrotron Radiat, Canadian Synchrotron Radiat Facil, Stoughton, WI 53589 USA

来源：

JOURNAL OF LUMINESCENCE | 2003年 / 105卷 / 01期

基金：

加拿大自然科学与工程研究理事会; 美国国家科学基金会;

关键词：

gold(I) complex; photoluminescence; XEOL; CK-edge NEXAFS;

D O I：

10.1016/S0022-2313(03)00093-0

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The luminescence of gold(I) complex [{-Ph2P(CH2)(2)Ph-2-AuNC5H4C5H4NAu-}(x)](2x+) [CF3CO2-](2x), in the solid state has been studied by soft X-ray excited optical luminescence and near-edge X-ray absorption fine structures at the C Kedge and we find that the origin of the luminescence is primarily from the 4,4'-bipyridine ligand facilitated by gold(I)-ligand interaction. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：21 / 26

页数：6

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