Efficient methano[70]fullerene/MDMO-PPV bulk heterojunction photovoltaic cells

被引：1079

作者：

Wienk, MM

Kroon, JM

Verhees, WJH

Knol, J

Hummelen, JC

van Hal, PA

Janssen, RAJ

机构：

[1] Energy Res Ctr Netherlands ECN, Solar Energy, NL-1755 ZG Petten, Netherlands

[2] Univ Groningen, Stratingh Inst, NL-9747 AG Groningen, Netherlands

[3] Univ Groningen, MSC, NL-9747 AG Groningen, Netherlands

[4] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 29期

关键词：

charge transfer; fullerenes; polymers; solar cells; time-resolved spectroscopy;

D O I：

10.1002/anie.200351647

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Owing to their increased absorption of light in the visible region, [70]fullerene derivatives provide a high photocurrent when incorporated as the electron acceptor in thin-film polymer photovoltaic cells. An incident-photon-to-current efficiency of 66% is obtained when [70]PCBM (see picture) is used in combination with a poly (p-phenylene vinylene). These high currents originate from an ultrafast charge transfer that occurs upon photoexcitation of either the fullerene or the polymer.

引用

页码：3371 / 3375

页数：5

共 24 条

[1] PHOTOPHYSICAL PROPERTIES OF C-70
ARBOGAST, JW
FOOTE, CS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) : 8886 - 8889
[2] Effect of LiF/metal electrodes on the performance of plastic solar cells
Brabec, CJ
Shaheen, SE
Winder, C
Sariciftci, NS
Denk, P
[J]. APPLIED PHYSICS LETTERS, 2002, 80 (07) : 1288 - 1290
[3] Brabec CJ, 2001, ADV FUNCT MATER, V11, P374, DOI 10.1002/1616-3028(200110)11:5<374::AID-ADFM374>3.0.CO
[4] 2-W
[5] Tracing photoinduced electron transfer process in conjugated polymer/fullerene bulk heterojunctions in real time
Brabec, CJ
Zerza, G
Cerullo, G
De Silvestri, S
Luzzati, S
Hummelen, JC
Sariciftci, S
[J]. CHEMICAL PHYSICS LETTERS, 2001, 340 (3-4) : 232 - 236
[6] GANGSTROM M, 1998, NATURE, V395, P257
[7] PREPARATION AND CHARACTERIZATION OF FULLEROID AND METHANOFULLERENE DERIVATIVES
HUMMELEN, JC
KNIGHT, BW
LEPEQ, F
WUDL, F
YAO, J
WILKINS, CL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (03) : 532 - 538
[8] Enhanced electron injection in organic electroluminescence devices using an Al/LiF electrode
Hung, LS
Tang, CW
Mason, MG
[J]. APPLIED PHYSICS LETTERS, 1997, 70 (02) : 152 - 154
[9] Hybrid nanorod-polymer solar cells
Huynh, WU
Dittmer, JJ
Alivisatos, AP
[J]. SCIENCE, 2002, 295 (5564) : 2425 - 2427
[10] ULTRAFAST SPECTROSCOPIC STUDIES OF PHOTOINDUCED ELECTRON-TRANSFER FROM SEMICONDUCTING POLYMERS TO C-60
KRAABEL, B
MCBRANCH, D
SARICIFTCI, NS
MOSES, D
HEEGER, AJ
[J]. PHYSICAL REVIEW B, 1994, 50 (24): : 18543 - 18552

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