New convergence criterion for multi-variable curve resolution

被引：4

作者：

Gan, F

Hopke, PK

机构：

[1] Clarkson Univ, Dept Chem Engn, Potsdam, NY 13699 USA

[2] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

来源：

ANALYTICA CHIMICA ACTA | 2003年 / 495卷 / 1-2期

关键词：

convergence criterion; multivariable curve resolution; completion;

D O I：

10.1016/j.aca.2003.08.019

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The traditional convergence criterion of the minimized sum of squared residuals does not always provide sufficient information to properly terminate the iterative process used in the multi-variable curve resolution problem. Thus, a new convergence criterion is proposed. The resolution results for both simulated and the real chromatographic system data show that the new convergence criterion can provide a better indication of the completion of the resolution process. (C) 2003 Elsevier B.V. All rights reserved.

引用

收藏

页码：195 / 203

页数：9

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