An approach to the cephalotaxine ring skeleton using an ammonium ylide Stevens [1,2]-rearrangement

被引：28

作者：

Beall, LS ^{[1
]}

Padwa, A ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 24期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(98)00774-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ammonium ylides derived from the Cu(II)-catalyzed decomposition of alpha-diazo carbonyls tethered to tertiary amines underwent a benzylic Stevens [1,2]-rearrangement to give tetrahydro isoquinolines or benzazepines containing fused five-membered rings, a feature found in the cephalotaxus and lycorane alkaloids. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4159 / 4162

页数：4

共 29 条

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