Photoinitiated cross-linking of acetylene-containing polymers in the presence of tungsten hexacarbonyl

被引：7

作者：

Badarau, C ^{[1
]}

Wang, ZY ^{[1
]}

机构：

[1] Carleton Univ, Dept Chem, Ottawa, ON K1S 5B6, Canada

来源：

MACROMOLECULES | 2003年 / 36卷 / 19期

关键词：

D O I：

10.1021/ma034657r

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Efficient photo-cross-linking of acrylate-type polymers having the ethynyl groups in the side chain in the presence of W(CO)6 was demonstrated. This new photo-cross-linkable system serves as a model for further development of various types of photo-crosslinkable polymers.

引用

页码：6959 / 6961

页数：3

共 21 条

[1]

COHEN MS, 1966, Patent No. 3254115

[2] PHOTOCHEMISTRY OF [W(CO)5(C(OME)PH)] - FORMATION OF ALKYNE CARBENE COMPLEXES AND STUDIES OF THEIR DECOMPOSITION REACTIONS [J].