Preparation of Cu2O particles with different morphologies and their application in lithium ion batteries

被引：84

作者：

Fu, L. J. ^{[1
,2
]}

Gao, J. ^{[1
,2
]}

Zhang, T. ^{[1
,2
]}

Cao, Q. ^{[1
,2
]}

Yang, L. C. ^{[1
,2
]}

Wu, Y. P. ^{[1
,2
,3
]}

Holze, R. ^{[3
]}

Wu, H. Q. ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

[3] Tech Univ Chemnitz, Inst Chem, D-09111 Chemnitz, Germany

来源：

JOURNAL OF POWER SOURCES | 2007年 / 174卷 / 02期

基金：

中国国家自然科学基金;

关键词：

morphology; crystallinity; electrochemical performance; Cu2O; core-shell;

D O I：

10.1016/j.jpowsour.2007.06.030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For the first time Cu2O particles with different morphologies are synthesized by adopting a polyol process performed at different temperatures. SEM and TEM show that the samples obtained at 140 and 160 degrees C present a core-shell structure. XRD measurements indicate that both samples exhibit better crystallinity compared with the samples obtained at 120 degrees C. Results from charge-discharge experiments and cyclic voltammograms (CV) reveal that morphology and crystallinity play important roles in determining the electrochemical performance Of Cu2O samples. (C) 2007 Published by Elsevier B.V.

引用

页码：1197 / 1200

页数：4

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