Synthetic hydromagnesite as flame retardant.: A study of the stearic coating process

被引:24
作者
Haurie, L
Fernández, AI
Velasco, JI
Chimenos, JM
Ticó-Grau, JR
Espiell, F
机构
[1] Univ Barcelona, Unitat Ciencia Mat & Engn Met, E-08028 Barcelona, Spain
[2] Univ Politecn Catalunya, Ctr Catala Plast, Barcelona 08222, Spain
[3] Univ Barcelona, Fac Farm, E-08028 Barcelona, Spain
关键词
coatings; fillers; flame retardance; thermogravimetric analysis (TGA); thermoplastics;
D O I
10.1002/masy.200550317
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A synthetic hydromagnesite obtained from an industrial by-product rich in magnesium oxide was employed and evaluated as a nonhalogenated flame retardant for poly(ethylene-co-vinyl acetate). The filler was characterized with different techniques (such as specific surface area, TGA, particle morphology and size measurements, WAXS). Significant differences were found between the synthetic hydromagnesite and the natural one. Synthetic hydromagnesite was coated with stearic acid and the effectiveness of the coating process was studied by the dye adsorption method and sedimentation volume measurements. The amount of coating agent ranged from 1 to 4.5%. This factor was found to have a significant effect on the therinal decomposition behaviour of the filler. A poly(ethylene-co-vinyl acetate) (27% of VA) was filled with the coated synthetic grades of hydromagnesite as well as with two commercial flame retardants and different physicochernical properties were evaluated, including their flame retardant effect.
引用
收藏
页码:165 / 174
页数:10
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