Structural isomerism in R3PSe(Ph)I compounds:: the ionic structure of [(Me2N)3PSePh]I

被引：16

作者：

Godfrey, SM ^{[1
]}

Ollerenshaw, RTA ^{[1
]}

Pritchard, RG ^{[1
]}

Richards, CL ^{[1
]}

机构：

[1] Univ Manchester, Inst Sci & Technol, Dept Chem, Manchester M60 1QD, Lancs, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 05期

关键词：

D O I：

10.1039/b100882j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of two mole equivalents of (Me2N)(3)P with Ph2Se2I2 produces the ionic compound [(Me2N)(3)PSePh]I which contains a long Se-I contact, 3.825(1) Angstrom, and a bent P-Se-I angle, 114.5(2)degrees.

引用

页码：508 / 509

页数：2

共 22 条

[1] Crystal structure of triphenylphosphine sulfide diiodine;: the first crystallographically characterised 1:1 molecular charge-transfer complex of a tertiary phosphine sulfide with diiodine [J].

Apperley, DC ;

Bricklebank, N ;

Burns, SL ;

Hibbs, DE ;

Hursthouse, MB ;

Malik, KMA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (08) :1289-1292

[2]

Arca M, 1998, Z ANORG ALLG CHEM, V624, P745, DOI 10.1002/(SICI)1521-3749(199804)624:4<745::AID-ZAAC745>3.0.CO

[3]

2-P

[4]

BIGOLI F, 1994, GAZZ CHIM ITAL, V124, P445

[5] The reaction of N-methylbenzothiazole-2-selone and 1,1-dimethylselenourea with sulfuryl chloride and dichlorine [J].

Boyle, PD ;

Godfrey, SM ;

Pritchard, RG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (23) :4245-4250

[6] Further structural motifs from the reactions of thioamides with diiodine and the interhalogens iodine monobromide and iodine monochloride: an FT-Raman and crystallographic study [J].

Boyle, PD ;

Christie, J ;

Dyer, T ;

Godfrey, SM ;

Howson, IR ;

McArthur, C ;

Omar, B ;

Pritchard, RG ;

Williams, GR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (18) :3106-3112

[7]

Boyle PD, 2000, J CHEM SOC DALTON, P1959

[8] The structural characterisation of Ph3PSe(Ph)I.: The first charge transfer (CT) complex of a tertiary phosphine containing a pseudohalogen [J].

Boyle, PD ;

Godfrey, SM ;

McAuliffe, CA ;

Pritchard, RG ;

Sheffield, JM .

CHEMICAL COMMUNICATIONS, 1999, (21) :2159-2160

[9]

Boyle PD, 2000, ANGEW CHEM INT EDIT, V39, P1796, DOI 10.1002/(SICI)1521-3773(20000515)39:10<1796::AID-ANIE1796>3.0.CO

[10]

2-G

← 1 2 3 →