A Ru( terpy)(phen)-incorporating ring and its light-induced geometrical changes

被引：17

作者：

Bonnet, S ^{[1
]}

Collin, JP ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] Univ Strasbourg 1, Inst Le Bel, CNRS, Lab Chim Organominerale,UMR 7513, F-67000 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 25期

关键词：

D O I：

10.1039/b503411f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Ru( terpy)( phen) motif has been inscribed in a 39-membered ring by functionalizing the ligands and subsequently performing a cyclization reaction on the complex; by visible light irradiation, a dramatic geometrical changeover of the cyclic complex takes place which can be reversed thermally.

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收藏

页码：3195 / 3197

页数：3

相关论文

共 31 条

[1] Rotaxanes incorporating two different coordinating units in their thread:: Synthesis and electrochemically and photochemically induced molecular motions [J].

Armaroli, N ;

Balzani, V ;

Collin, JP ;

Gaviña, P ;

Sauvage, JP ;

Ventura, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4397-4408

[2]

Ashton PR, 2000, CHEM-EUR J, V6, P3558, DOI 10.1002/1521-3765(20001002)6:19<3558::AID-CHEM3558>3.0.CO

[3]

2-M

[4] A PHOTOCHEMICALLY DRIVEN MOLECULAR MACHINE [J].

BALLARDINI, R ;

BALZANI, V ;

GANDOLFI, MT ;

PRODI, L ;

VENTURI, M ;

PHILP, D ;

RICKETTS, HG ;

STODDART, JF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1993, 32 (09) :1301-1303

[5]

Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO

[6]

2-X

[7] Artificial molecular-level machines. Dethreading-rethreading of a pseudorotaxane powered exclusively by light energy [J].

Balzani, V ;

Credi, A ;

Marchioni, F ;

Stoddart, JF .

CHEMICAL COMMUNICATIONS, 2001, (18) :1860-1861

[8]

Balzani V., 2003, Molecular Devices and Machines, a Journey into the Nanoworld

[9] A photochromic system based on photochemical or thermal chelate exchange on Ru(phen)2L2+ (L = diimine or dinitrile ligand) [J].

Baranoff, E ;

Collin, JP ;

Furusho, Y ;

Laemmel, AC ;

Sauvage, JP .

CHEMICAL COMMUNICATIONS, 2000, (19) :1935-1936

[10] Photochemical expulsion of the neutral monodentate ligand L in Ru(terpy*)(diimine)(L)2+:: A dramatic effect of the steric properties of the spectator diimine ligand [J].

Bonnet, S ;

Collin, JP ;

Sauvage, JP ;

Schofield, E .

INORGANIC CHEMISTRY, 2004, 43 (26) :8346-8354

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