Rhodium versus ruthenium:: contrasting behaviour in the asymmetric transfer hydrogenation of α-substituted acetophenones

被引：76

作者：

Cross, DJ

Kenny, JA

Houson, I

Campbell, L

Walsgrove, T

Wills, M ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Avecia Huddersfield Works, Huddersfield HD2 1FF, W Yorkshire, England

[3] GlaxoSmithKline, Tonbridge TN11 9AN, Kent, England

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0957-4166(01)00313-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of a number of alpha -substituted acetophenones has been achieved using both ruthenium(II)- and rhodium(III) -based asymmetric transfer hydrogenation catalysts employing formic acid as the hydrogen donor. (C) 2001 Elsevier Science Ltd. All rights reserved.

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页码：1801 / 1806

页数：6

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