Spin-orbit splitting and critical point energy at Γ and L points of cubic CdTe nanoparticles:: Effect of size and nonspherical shape -: art. no. 115413

This study reports the observation of changes in critical point energy at Gamma and L points and an increase in spin-orbit splitting energy of cubic CdTe nanoparticles in comparison to the bulk single-crystal value. epsilon(1) and epsilon(2) spectra of CdTe nanoparticles, accurately derived from spectroscopic ellipsometry measurements on CdTe nanoparticles dispersed in SiO2 films, show E-0, E-0+Delta(0), E-1, and E-1+Delta(1) critical points at 1.75, 2.74, 3.29, and 3.83 eV, respectively. Glancing-angle x-ray diffraction and high-resolution transmission electron microscopy investigations confirm cubic CdTe nanoparticles with good crystallinity and a nonspherical shape. Variable magnitudes of size-induced stress along the minor and major axes cause dissimilar shifts of heavy-hole and split-off bands resulting in a positive contribution to spin-orbit splitting energy, in addition to the small size.