Comparison of comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry and gas chromatography-mass spectrometry for the analysis of tobacco essential oils

被引：31

作者：

Zhu, SK

Lu, X

Xing, J

Zhang, SW

Kong, HW

Xu, GW

Wu, CY ^{[1
]}

机构：

[1] Wuhan Univ, Dept Chem, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatogr R&A Ctr, Dalian 116011, Peoples R China

来源：

ANALYTICA CHIMICA ACTA | 2005年 / 545卷 / 02期

关键词：

gas chromatography-mass spectrometry; comprehensive two-dimensional gas chromatography; GC x GC; time-of-flight mass spectrometry; coupled columns; essential oil;

D O I：

10.1016/j.aca.2005.04.070

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A sample of tobacco essential oil was analyzed using gas chromatography-mass spectrometry (GUMS)and comprehensive two-dimensional gas chromatography coupled to a time-of-flight mass spectrometry (GC x GC/TOFMS), respectively. In the GUMS analysis, serially coupled columns were used. By comparing the GUMS results with GC x GC/TOFMS result,,, many more components in the essential oil could be found within the two-dimensional separation space of GC x GC. The quantitative determination of components in the essential oil was performed by GC x GC with flame ionization detection (FID), using a method of multiple internal standards calibration, (c) 2005 Elsevier B.V. All rights reserved.

引用

收藏

页码：224 / 231

页数：8

相关论文

共 21 条

[1] Comprehensive two-dimensional gas chromatography of complex samples by using a 'reversed-type' column combination: application to food analysis [J].

Adahchour, M ;

Beens, J ;

Vreuls, RJJ ;

Batenburg, AM ;

Brinkman, UAT .

JOURNAL OF CHROMATOGRAPHY A, 2004, 1054 (1-2) :47-55

[2] Comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometric detection for the trace analysis of flavour compounds in food [J].

Adahchour, M ;

van Stee, LLP ;

Beens, J ;

Vreuls, RJJ ;

Batenburg, MA ;

Brinkman, UAT .

JOURNAL OF CHROMATOGRAPHY A, 2003, 1019 (1-2) :157-172

[3]

BURDOCK GA, 1994, FENAROLIS HDB FLAVOR, V1

[4] Polarity changes during capillary gas chromatographic and gas chromatographic mass spectrometric analysis using serially coupled columns of different natures and temperature programming - Application to the identification of constituents of essential oils [J].

Chanegriha, N ;

Baaliouamer, A ;

Rolando, C .

JOURNAL OF CHROMATOGRAPHY A, 1998, 819 (1-2) :61-65

[5] Unravelling the composition of very complex samples by comprehensive gas chromatography coupled to time-of-flight mass spectrometry -: Cigarette smoke [J].

Dallüge, J ;

van Stee, LLP ;

Xu, XB ;

Williams, J ;

Beens, J ;

Vreuls, RJJ ;

Brinkman, UAT .

JOURNAL OF CHROMATOGRAPHY A, 2002, 974 (1-2) :169-184

[6] CONCEPTS AND COMPARISONS IN MULTIDIMENSIONAL SEPARATION [J].

GIDDINGS, JC .

JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY & CHROMATOGRAPHY COMMUNICATIONS, 1987, 10 (05) :319-323

[7] Analysis of cigarette smoke condensates by comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry 1 acidic fraction [J].

Lu, X ;

Cai, JL ;

Kong, HW ;

Wu, M ;

Hua, RX ;

Zhao, MY ;

Liu, JF ;

Xu, GW .

ANALYTICAL CHEMISTRY, 2003, 75 (17) :4441-4451

[8] Principles and applications of comprehensive two-dimensional gas chromatography [J].

Marriott, P ;

Shellie, R .

TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2002, 21 (9-10) :573-583

[9] Gas chromatographic technologies for the analysis of essential oils [J].

Marriott, PJ ;

Shellie, R ;

Cornwell, C .

JOURNAL OF CHROMATOGRAPHY A, 2001, 936 (1-2) :1-22

[10]

Mondello L, 1999, HRC-J HIGH RES CHROM, V22, P350, DOI 10.1002/(SICI)1521-4168(19990601)22:6<350::AID-JHRC350>3.0.CO